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Apache
First confrontation:
Episode
Unknown
Manga Unknown Apache first encountered Matsumoto during the Hueco Mundo arc. She, alongside Mila-Rose and Sun-Sun, took on Matsumoto to help defend their mistress, Tia Harribel. |
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Ashisogi Jizo
First confrontation:
Episode
Unknown
Manga Unknown One of the rogue Zanpakuto, belonging to Mayuri Kurotsuchi, Ashisogi Jizo, alongside the other Zanpakuto, attempted to take over Soul Society, in full opposition of the Gotei 13. |
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Ayon
First confrontation:
Episode
Unknown
Manga Unknown Ayon was the creature summoned by Apache, Mila-Rose, and Sun-Sun throug the removal of their left arms. A frightening creature, he almost killed Matsumoto during their battle. |
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Byakuya Kuchiki
First confrontation:
Episode
Unknown
Manga Unknown Byakuya recently turned against The Soul Society during the Zanpakuto Arc, and sided with Muramasa's Rebellion against the Gotei 13. Although never directly fighting Matsumoto, he DID support Muramasa's opposition towards the Gotei 13. |
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Fūrā
First confrontation:
Episode
Unknown
Manga Unknown A giant creature summoned by Wonderweiss Magrera during the final showdown at Karakura Town. Although never directly opposing Matsumoto, he was summoned by Wonderweiss, who WAS an opponent of Matsumoto. |
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Grimmjow Jaegerjaques
First confrontation:
Episode
Unknown
Manga Unknown Grimmjow Jaegerjaques was the 6th Espada under Sousuke Aizen. Although never explicitly opposing Matsumoto, he nevertheless supported the Arrancar's opposition to the Gotei 13, and was accompanied by Shawlong Qu Fong, who DID face Matsumoto. |
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Haineko
First confrontation:
Episode
Unknown
Manga Unknown One of the rogue Zanpakuto, Haineko was Matsumoto's very own zanpakuto. Alongside Tobiume, she fought with Matsumoto during the Zanpakuto Arc, alongside Muramasa' rebellion. |
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Luppi
First confrontation:
Episode
Unknown
Manga Unknown Luppi came to Karakura Town after Grimmjow was removed from his position as 6th Espada. There he encountered Matsumoto and Hitsugaya, and engaged in a battle with the two. |
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Mila-Rose
First confrontation:
Episode
Unknown
Manga Unknown One of Harribel's Fraccion. Alongside Apache and Sun-Sun, she faced off against Matsumoto to protect her mistress, summoning Ayon in the proccess. |
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Muramasa
First confrontation:
Episode
Unknown
Manga Unknown Muramasa was the leader of the Zanpakuto Rebellion, and caused Matsumoto's Zanpakuto Haineko to leave her side. |
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Senbonzakura
First confrontation:
Episode
Unknown
Manga Unknown Senbonzakura is the Zanpakuto of Byakuya Kuchiki. Although never explicitly opposing Matsumoto, he did support Muramasa's rebellion against the Gotei 13. |
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Shawlong Qu Fong
First confrontation:
Episode
Unknown
Manga Unknown Shawlong Qu Fong was one of the first Arrancar to arrive on Earth, where he fought against Rangiku Matsumoto. |
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Sousuke Aizen
First confrontation:
Episode
Unknown
Manga Unknown Leader of the Arrancars and their opposition to the Gotei 13. He created the Arrancars, who would eventually fight Matsumoto. |
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Sun-Sun
First confrontation:
Episode
Unknown
Manga Unknown One of Harribel's Fraccion. Alongside Apache and Mila-Rose, she fought Matsumoto to protect her mistress, and during the course of the battle summoned Ayon. |
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Tier Halibel
First confrontation:
Episode
Unknown
Manga Unknown Harribel was the 3rd Espada under Sousuke Aizen. Her Fraccion faced off against Matsumoto during the Battle for Karakura Town, and she supported Aizen's opposition of the Gote 13. |
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Tobiume
First confrontation:
Episode
Unknown
Manga Unknown One of the Zanpakutou who joined Muramasa during the Zanpakutou Rebellion, she belonged to Momo Hinamori. Alongside Haineko, she fought Matsumoto during this arc. |
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Yammy Llargo
First confrontation:
Episode
Unknown
Manga Unknown Yammy was the 10th Espada under Sousuke Aizen, and a supporter of his opposition towards the Gotei 13, although never outright fighting Matsumoto. |