@SMXLR8: There's no way he would break Captain America's arms through the shield. Vibranium prevents that. But yeah I could see Cap losing.
@Stingerrain: yeah i dont blame you, at the start we all think venom is around spiderman's level but spidey mostly exploits venom's weaknesses all the time to win, here is something that might help you change your perspective
Can't forget this either.
Granted he got curbstomped literally. But even Juggy failed to actually kill him.