@taichokage: i'm not gonna lie, that's impressive and has me thinking Aizen is pretty awesome but i still think Madara will at least stand a chance, i see chakra as a form of Reiatsu, sort of like the opposite though reiatsu is the effect of being powerful while chakra is the cause, anyway i think madara's chakra will protect him against the damaging effects of Aizen's reiatsu allowing him to get close ( of course this is speculation since we dont know what would really happen) and madara managed to completely control the Fourth Mizukage with his sharingan, as i mentioned in an above post, sharingan users have been shown to be capable of seeing through all types of illusions including Aizen's. yes izangi is cast on the user instead of the opponent but the user can literally make his own death an illusion however that being said i'm still not positive Madara could win, i'm simply stating it'll be a better match up than some give it credit for being
as for Orochimaru vs mayuri i think mayuri still doesn't stand a chance
yes he's faster but orochimaru has tons of moves up his sleeve, you mention quality over quanity but the quality of orochimaru's jutsu is great as well, he is a master at every move he's learned. he has been shown to be strong enough to kick a tree and knock it down unaided, he is immortal to virtually all forms of injury, he has been cut in half, poisoned, and punched by Tsunade (who has super strength) and survived, he has been paralyzed before by the third hokage and still was a dangerous opponent, and as for Mayuri's bankai, it is quite a target, while it poisons anything in the area, it can be blown up or impalled. while mayuri's super sense poison is deadly, he only beat szayel with it by having him consume nemu, orochimaru wouldn't try to do that and would also keep good distance between attacks with wind release great breaktrhough he can level entire areas with one blast. he can create the three rashamon gates that can block most blasts like kido. he can shed his skin to heal from all attacks, and actually become a giant snake composed of smaller snakes, if he is cut his blood is poisonous to whoever it gets on.