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A pentagram is a five pointed star with five strokes and it can represent many things in religion and anime.
OverviewIn anime and manga series, a pentagram is a symbolic concept that can represent various things just like the real world with their religions.
Do not confused it with a Pentacle (a pentagram inside a circle)
Shaman KingA pentagram represents the five elements: fire, rain, thunder, earth, and wind. It correlates with the five grand elemental spirits and the shamans who are chosen.
Hao Asakura is a known shaman who master the pentagram and uses the spirit of fire.