Marianne is a Rinne that take a doll form.
Marianne is the "Hunter" Friagne beloved Rinne (means Friagne loves her), and she's the reason that Friagne wants to perform the City Devourer, to make her become a Guze no Tomogara that doesn't need Power of Existence supplies from the master. When she fight Shana, she sacrifices herself for her master, Friagne, and make Friagne shoots Shana, only being incinerate by Tenjo no Goka, Alastor.
She's voiced by Kimiko Koyama.
Shakugan no Shana the Movie
Shakugan no Shana: the Movies the first animated film based on the Shakugan no Shana series.