"Broly easily. He is far more powerful than Thor. Even as a child he was able to tank the explosion of a planet. He can pop planets the way ppl pop zitz. He destroyed a galaxy. And was fully immersed in lava with no ki barrier Thor would fall to most all of Broly's powerful attacks. "
No. Thor will block Brolys attacks with a vortex (which stopped a life bomb that wouldve destroyed 1/5th of a universe and a null bomb which can destroy a galaxy). Thor also has nanosecond or faster reflexes.