I found out where this image comes from. It's from the Regal Mammoth arc where Coco just came on Kiss and saves them from the black ball Gourmet Beasts. It's episode 12 for us while episode 13 on Toriko Wikia.
Coco is one of the Four Heavenly Kings and one of the main characters in the series with almost as many appearances as Toriko. He is the most intelligent of the Kings.
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