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This is an alternate, evil, grown-up form of Chibi-Usa.
Chibi-Usa is kidnapped by the Wiseman. He casts a spell which warps her memories of her family and friends, turning them into cruel, unhappy ones. Chibi-Usa's body transforms into that of a beautiful, adult woman with a black, upside-down crescent moon on her forehead. She maintains her relationship with Luna-P--in fact, it bears a black, upside-down crescent moon to match hers. She is extremely powerful and proves a daunting enemy for the senshi who cannot bring themselves to hurt her because she is Chibi-Usa.